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Product Data Sheet — 1,3-Dioxolane

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1,3-Dioxolane (CAS: 646-06-0)

Common Names: Dioxolane, Ethylene glycol methylene ether, Formaldehyde ethylene acetal

A polar aprotic cyclic diether with active solvency 1,3-Dioxolane is a highly polar aprotic (no hydroxyl functionality) solvent, having low toxicity. The moderate boiling point allows for easy separation and recovery from reaction mixtures. Novolyte offers the highest purity (99.9%, (99.95% typical), low peroxide (5ppm max), and low moisture (150ppm max).

Physical Properties

Empirical Formula C3H6O
Molecular Weight 74.1
Boiling Point (°C 760 mm Hg) 75.6
Freezing Point (°C) -95
Specific Gravity (20°C) 1.066
Vapor Pressure (mm Hg/20°C) 82
Volatility (n-butylacetate = 100) 350
Viscosity (cp 20°C) 0.6
Surface Tension (dynes/cm 20°C) 34.05
Explosive limits (Lower limit, v/v)
(Upper limit, v/v)
2%
21%
Auto Ignition temp (°C) 274
Heat of Vaporization (Kcal/mole) 8.4
Heat of Combustion (K Cal/mole) 406
Henry's Law Constant (atm m3/mol) 2.4 x10-5
Flash Point (°C, closed cup) -6
Refractive Index (20°C) 1.3974

Appearance: Clear, Colorless

Odor: Ethereal

Solubility at 25°C

  • In water: complete
  • Water in: complete

Process solvent

  • For inks and dyes
  • For adhesives and coating
  • Electrolyte solutions for lithium batteries
  • Dielectric constant = 7.34
  • Foam production
  • To dissolve the resins of polar polymers
  • Useful for surface modification of polymers

Reaction solvent

  • At near pH 7
  • Reactant to serve as a source of CH2
  • Acting as a polycarbonate and other polar polymer swelling agent

Features

  • Aprotic
  • Moderate boiling point
  • Water soluble
  • High solvency characteristics
  • Powerful diluent
  • Friendly tox profile
  • Refer to MSDS for detailed handling and disposal information
  • Use with proper PPE and engineering controls