Technical Resources

energy storage solutions

Product Data Sheet — Ethyl Glyme

Download this data sheet

Ethyl Glyme (CAS: 629-14-1)

Ethylene glycol dimethyl ether CH3CH2OCH2CH2OCH2CH3

An aprotic glycol diether with active solvency and formulating versatility Ethyl diglyme is unique among ethylene oxide based solvents in that it is aprotic (no hydroxyl functionality). As a result it is a relatively inert solvent with outstanding stability at high pH. The lmoderate boiling point allows for easy separation from reaction mixtures and recovery. Used as a solvent for Organometallic reactions involving reductions, alkylations, Grignard and in reactions involving alkali metals. Take advantage of its partial water solubility for purification.

Physical Properties

Empirical Formula C6H14O2
Molecular Weight 118.18
Boiling Point (°C 760 mm Hg) 121
Freezing Point (°C) -74
Specific Gravity (20°C) 0.8417
Vapor Pressure (mm Hg/20°C) 9.0
Volatility (n-butylacetate = 100) 105
Viscosity (cp 20°C) 0.7
Surface Tension (dynes/cm 20°C) 23.8
Flash Point (°C, closed cup) 27
Refractive Index (20°C) 1.3922

Appearance: Clear

Odor: Ethereal

Solubility at 25°C

  • In water: 20.4%
  • Water in: 3.3%

Reaction solvent for:

  • Organometallics for API synthesis
  • Grignard reagents
  • Synthesis and reaction of organolithium reagents

Features

  • Aprotic
  • Moderate boiling point
  • Partially water soluble
  • High solvency characteristics
  • Excellent thermal and chemical stability
  • Refer to MSDS for detailed handling and disposal information
  • Use with proper PPE and engineering controls